This is not an error. Cracking breaks large molecules into smaller
ones, and smaller molecules take up more room, so a refinery returns more
volume than it receives. The EIA reports it as a line item called processing
gain, and at the foot of the diagram you can see it: the red bar runs past
the black one.
Below is every major step between the two, drawn as descent. Crude at the top,
one ancestor. The first split is the only purely physical one in the whole
process; everything after it is chemistry. At the bottom, lines rejoin,
because the gasoline in your tank has at least four separate lineages.
How to read it
Red means measured. Every red figure is an EIA refinery yield.
Nothing inferred or drawn for structure is ever red.
Width means volume, and only at the two ends. No line in the middle
carries a quantity, because no intermediate quantity is published. Drawing one
would be a guess wearing the costume of a measurement.
Dashed red is hydrogen. It runs backwards up the diagram: the
reformer makes the hydrogen that cleans its own feed. Refining is not a tree,
and that loop is why.
Line weight is charge capacity, and the figure under a unit is that
capacity as a share of crude distillation. These are a different kind of
number from the yields: capacity is what a unit is built to process, not what
it processed. Potential, not actual.
How much each lane can process
Unit
Capacity
Share of crude
Catalytic hydrotreating, distillate
6,268,465 b/sd
32.7%
Catalytic cracking, fresh feed
5,334,708
27.8%
Catalytic hydrotreating, naphtha / reformer feed
4,490,487
23.4%
Catalytic reforming
3,549,453
18.5%
Coking, delayed and fluid
2,793,645
14.6%
Catalytic hydrocracking, gas oil
1,468,600
7.7%
Visbreaking
16,000
0.1%
Those come to 124.8% of crude distillation capacity. It is the second
thing in this diagram that looks like an error and is not. It exceeds 100%
because a barrel's components are processed more than once: gas oil is
cracked, and the product is hydrotreated again before it is blended. The
barrel gets bigger, and it gets handled more times than there is barrel.
What these units actually do
Cracking, coking, reforming. The names are trade words, but there
are only four things any of them can do to a molecule: cut it up, stick it
together, change its shape, or take the sulfur out. Everything in the diagram
is one of those.
Separating
No chemistry at all. Heat the crude and the lighter molecules boil off first, so the barrel sorts itself by boiling point. Everything after this step changes the molecules.
Atmospheric distillation 100% of the barrel
Splits by boiling point. The first and last purely physical split.
Vacuum distillation
Re-boils the atmospheric residue under vacuum, below its cracking temperature.
Breaking
Big molecules into small ones. The heavy end of a barrel is worth little and there is a lot of it, so refineries break it apart. This is where the extra volume comes from: two small molecules take up more room than the one big molecule they came from.
Fluid catalytic cracker 28% of the barrel
Breaks gas oil into lighter molecules. Where most of the extra volume comes from.
Coker 15% of the barrel
Cracks the vacuum residue until what is left is solid carbon.
Hydrocracker 8% of the barrel
Cracks under hydrogen. Favours jet and diesel over gasoline.
Rearranging
Same molecule, different shape. Octane is not about size but about how a molecule is built, so these units take a low-octane stream and fold it into a high-octane one without making it any bigger.
Catalytic reformer 18% of the barrel
Rearranges heavy naphtha into aromatics. Makes the hydrogen the hydrotreaters need.
Isomerization 4% of the barrel
Rearranges light naphtha into higher-octane shapes. Same size, better structure.
Joining
Small molecules into bigger ones. The gases left over from cracking are too light to put in a tank, so they are stitched together into something that belongs in gasoline.
Alkylation 7% of the barrel
Runs the other way: joins small molecules into larger, high-octane ones.
Cleaning
Taking the sulfur out. Crude carries sulfur, sulfur becomes acid rain and poisons catalysts, and the limits are legal ones. Hydrogen pulls it out as hydrogen sulfide.
Distillate hydrotreater 33% of the barrel
The unit that made ultra-low-sulfur diesel possible.
Naphtha hydrotreater 23% of the barrel
Runs before the reformer, not after: sulfur poisons the reforming catalyst.
Desalter
Washes out salt and water before heat.
Kerosene hydrotreater
Sulfur out, on spec for jet.
What is absent
The visbreaker
US visbreaking capacity is 16,000 barrels a day against 2,793,645 for
coking. These yields are American, so a unit at 0.08% of the barrel is left
out rather than drawn at a scale it does not have. In Europe and Asia it
would belong.
Miscellaneous products, 0.5%
EIA's residual category. No single lineage produces it, so it is named
rather than given a parent it does not have.
Actual throughput
Capacity is published; what ran through it in a given month is not, at
this level of detail. So the lanes carry what they could process rather
than what they did. An earlier version of this page said no per-unit figure
existed at all, which was wrong.
Where the plastic is
Only 1.3% of the barrel is labelled petrochemical feedstock here, and that
is not how much oil becomes plastic. EIA names a product for what it is,
not where it goes, so the hydrocarbon gas liquids and still gas that feed
crackers are counted as themselves. Most US plastics feedstock is ethane
from shale gas, which never passes through a refinery and so cannot appear
in a refinery yield at all. Petrochemicals take about 16% of global oil
demand. None of that is answerable from this diagram, because the
destination is not in the source. It needs its own.